Why nitrogen nitrogen single bond is weaker than phosphorus phosphorus single bond?
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N-N sigma bond is weaker than P-P sigma bond due to the small bond length between the nitrogen atoms. The non-bonding electrons(lone pair of electrons) of both the atoms repel each other making it weaker than P-P sigma bond.
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here it is
Explanation:
N−N single bond is weaker than P−P bond due to smaller size of N as compared to P. Smaller size of N leads to smaller N−N bond length. As a result, the lone pair of electrons on the both the N atoms repel each other leading to unstability or weakening of N−N bond.
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