Chemistry, asked by ram227, 1 year ago

why PCL5 is exist and NCL5 is not exist

Answers

Answered by mintu15
1
Since nitrogen atom has no vacant 2d orbital in its configuration, it can extend its covalency only up to 5 . Therefore, NCl5 doesn't exist . But in case of phosphorous, an electron can be promoted from 3s filled orbital to 3d vacant orbitals . Therefore, phosphorus can extend its covalency to 5 . Therefore, a molecule PCl5 exists

ram227: thanks thanks thanks
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mintu15: See according to me if u want to do it well just read carefully whichever book that u have , clear ur doubts it's very important and check yourself by practicing more and more
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ram227: plz name some important books.
mintu15: Books of Dinesh and Pradeep
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