Working of calorimeter?
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Bomb calorimeters have to withstand the large pressure within the calorimeter as the reaction is being measured. Electrical energy is used to ignite the fuel; as the fuel is burning, it will heat up the surrounding air, which expands and escapes through a tube that leads the air out of the calorimeter.
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A calorimeter is an object used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity. Differential scanning calorimeters, isothermal micro calorimeters, titration calorimeters and accelerated rate calorimeters are among the most common types. A simple calorimeter just consists of a thermometer attached to a metal container full of water suspended above a combustion chamber. It is one of the measurement devices used in the study of thermodynamics, chemistry, and biochemistry.
To find the enthalpy change per mole of a substance A in a reaction between two substances A and B, the substances are separately added to a calorimeter and the initial and final temperatures (before the reaction has started and after it has finished) are noted. Multiplying the temperature change by the mass and specific heat capacities of the substances gives a value for the energygiven off or absorbed during the reaction. Dividing the energy change by how many moles of A were present gives its enthalpy change of reaction.
{\displaystyle q=C_{v}(T_{f}-T_{i})}
Where q is the amount of heat according to the change in temperature measured in joules and Cv is the heat capacity of the calorimeter which is a value associated with each individual apparatus in units of energy per temperature (Joules/Kelvin).
To find the enthalpy change per mole of a substance A in a reaction between two substances A and B, the substances are separately added to a calorimeter and the initial and final temperatures (before the reaction has started and after it has finished) are noted. Multiplying the temperature change by the mass and specific heat capacities of the substances gives a value for the energygiven off or absorbed during the reaction. Dividing the energy change by how many moles of A were present gives its enthalpy change of reaction.
{\displaystyle q=C_{v}(T_{f}-T_{i})}
Where q is the amount of heat according to the change in temperature measured in joules and Cv is the heat capacity of the calorimeter which is a value associated with each individual apparatus in units of energy per temperature (Joules/Kelvin).
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