Chemistry, asked by nkmysign1990, 2 months ago

In the first order decomposition of A : A  2B + 3C Concentration of A decrease from initial concentration 0.8M to 0.2M in 13.86 min. then calculate rate of appearance of B (in M/s) after 13.86 m​

Answers

Answered by abhi178
6

Given info : in the first order decomposition of A : A ⇒2B + 3C. concentration of A decrease from 0.8M to 0.2 M in 13.86 min.

To find : the rate of appearance of B after 13.86 min is ...

solution : reaction is A ⇒2B + 3C

∴ - d[A]/dt = +1/2 d[B]/dt = +1/3 d[C]/dt

means, rate of disappearance of A = 1/2 × rate of appearance of B ....(1)

a/c to question, concentration of A decreases from 0.8M to 0.2 M in 13.86 min.

so, rate of disappearance of A = - (0.2 - 0.8)/13.86 M/min = 0.6/13.86 M/min

now rate of appearance of B = 2 × rate of disappearance of A [ from eq (1). ]

= 2 × 0.6/13.86 = 1.2/13.86 = 0.0866 M/min = 0.0866/60 M/sec = 0.00144 M/s

Therefore the rate of appearance of B is 0.00144 M/s

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