Significant of Helmholte function :
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In thermodynamics, the Helmholtz free energy is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature and volume (isothermal, isochoric). ... If the volume were not held constant, part of this work would be performed as boundary work.
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The thermodynamic function of a system that is equal to its internal energy minus the product of its absolute temperature and entropy: a decrease in the function is equal to the maximum amount of work available during a reversible isothermal process.
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