In Cannizzaro reaction given below
2PhCHO □(→┴:OH)PhCH₂ OH + PhCO₂⊝
the slowest step is :
(a) the transfer of hydride to the carbonyl group
(b) the abstraction of proton from the carboxylic group
(c) the deprotonation of Ph CH₂OH
⊝
(d) the attack of : OH at the carboxyl group
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In any given cannizaro reaction the step including transfer of hydride ion to the carbonyl group is the slowest step.
- A given complex reaction can be broken down into a number of steps involving elementary reactions.
- The slowest step is the rate determining step of the given complex reaction.
- Since, the transfer of hydride ion tothe carbonyl group is the slowest step of the cannizaro reaction , is is also the rate determining step.
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